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液膜型ヒスタミンイオン選択性電極の作製
http://hdl.handle.net/10252/4852
http://hdl.handle.net/10252/48520ee2f3e0-00b6-41e3-8d57-207dc3480c2f
名前 / ファイル | ライセンス | アクション |
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分析化学28(11)_705-707.pdf (167.7 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-05-17 | |||||
タイトル | ||||||
タイトル | 液膜型ヒスタミンイオン選択性電極の作製 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Construction of liquid membrane type histamine ion-selective electrode. | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Histamine | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Ion-selective electrode | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Potentiometric titration | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
工藤, 恵
× 工藤, 恵× 片岡, 正光× 神原, 富民 |
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著者別名 | ||||||
姓名 | Kudoh, Megumu | |||||
著者別名 | ||||||
姓名 | Kataoka, Masamitsu | |||||
著者別名 | ||||||
姓名 | Kambara, Tomihito | |||||
書誌情報 |
分析化学 巻 28, 号 11, p. 705-707, 発行日 1979-11-05 |
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出版者 | ||||||
出版者 | 日本分析化学会 | |||||
ISSN / EISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0525-1931 | |||||
書誌ID(NCID) | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00222633 | |||||
テキストバージョン | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
日本十進分類法 | ||||||
主題Scheme | NDC | |||||
主題 | 433 | |||||
NIIサブジェクト | ||||||
主題Scheme | Other | |||||
主題 | 化学 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Construction of a liquid membrane type ion-selective electrode sensitive to divalent histaminium cation and its application to potentiometric titration are described. Histamine cation (abbreviated as H_2his^<2+>) forms an ion-pair with tetraphenylborate anion (abbreviated as TPB-) in aqueous phase. The extract shows the property of histamine cation-sensitive membrane. Platinized platinum electrode was employed as the internal reference electrode. The calibration curve of the electrode shows a Nernstian response for H_2his^<2+> ion in the concentration range from 10mM to 15μM. Effect of pH on the electrode potential was observed and the potential is almost constant over the pH range from 1.5 to 6.0. Selectivity coefficients of the histaminium ion-selective electrode was evaluated by means of the separate solution method. Some quaternary ammonium cations showed serious interferences. Sodium tetraphenylborate standard solution was successfully titrated with histamine solution potentiometrically by using the present electrode. |